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The magnetostructural coupling in off-stoichiometric MnCoGe alloys is realized within a wide Curie temperature window (up to 96 K) through tuning the Mn/Co ratio and it results in a significant entropy change (up to − 30.8 J K−1 kg−1). Two scenarios have been studied, i.e. the Co- and Mn-rich compositions, respectively. In both scenarios, the orthorhombic-hexagonal structural transition temperature...
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