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A composite coating of calcium phosphate/zirconia (CaPh/ZrO2) has been applied to the AZ91D magnesium alloy through electrolytic and annealing methods for enhancing corrosion resistance and bioactivity. The intermediate ZrO2 layer plays an important role in enhancing the adhesion strength of top CaPh layer on AZ91D as the condensation of hydroxyl bonds in Zr(OH)4 precursor, also leading to the reduction...
By a two-step fabrication process of electrolytic deposition and annealing treatment, an MgO/ZrO 2 duplex-layer coating has been prepared on AZ91D magnesium alloy as a protective film against corrosion. Owing to the chemical bonding formed after the condensation of precursory hydroxides, the adhesion strength, thickness and compactness of MgO coating on the substrate are significantly enhanced...
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