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We studied the kinetics and mechanism of the charge‐transfer polymerization of methyl methacrylate (MMA) initiated with n‐butyl amine (BA) and carbon tetrachloride (CCl4) catalyzed by palladium dichloride (PdCl2 or PdII) in a dimethyl sulfoxide medium by using a dilatometric technique at 60°C. The rate of polymerization (Rp) was a function of [MMA], [BA], [CCl4], and [PdII]. The kinetic data indicated...
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