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Kinetics and the carbon-13 kinetic isotope effects in the decarboxylation of phenylpropiolic acid in HCOOH/H2O, 1:1/V:V, solution have been examined between 80-140.13oC. 13C KIE in the decarbonylation of formic acid, proceeding with measurable rate in this medium between 130-150oC, has determined also and compared with corresponding values found in the pure HCOOH/H2O solution. Kinetics and C-13 KIE...
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