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The mechanism study of redox mediator to transfer the photogenerated electrons is extremely desirable for artificial Z-scheme photocatalytic systems. Here we find that the α-Fe2O3 exposed by {012} and {104} facets can facilitate the reduction of IO3−, which results in increasing the activity of photocatalytic water oxidation significantly. By employing NaIO3 as an electron acceptor, the O2 evolution...
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