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The electrodeposited precursor is a mixture of Cu, Sn, and Zn alloys, these elements form Cu6Sn5 and CuZn binary phases, and subsequently these phases transform into many binary and ternary intermediates, such as CuS, ZnS, Cu2SnS3, and Cu2ZnSnS4 (CZTS) at low annealing temperature in pure sulfur and H2S atmospheres. Finally, CZTS films can be completely formed by sulfidizing at 550 °C for 1 h in pure...
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