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The 2‐carboxy‐6‐hydroxyoctahydroindole moiety is an essential residue for the antithrombotic activity of aeruginosins, which are a class of cyanobacteria‐derived bioactive linear tetrapeptides. The biosynthetic pathway of the 2‐carboxy‐6‐hydroxyoctahydroindole moiety has not yet been resolved. AerF was indicated to be involved in the biosynthesis of the 2‐carboxy‐6‐hydroxyoctahydroindole moiety. This...
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