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ZnS hollow nanospheres with holes were prepared by reacting ZnSO4 with H2S, the sulfide source formed in the reaction of CS2 with ethylenediamine, 1,3-propylenediamine, butylamine or 2-(2-aminoethylamino) ethanol, which also acted as a template agent, at 50°C under agitation. The shape, particle size of about 100–850 nm and hole size of about 150–600 nm of ZnS hollow nanospheres with holes were shown...
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