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Background
Colorectal cancer (CRC) presents a significant global health burden, characterized by a heterogeneous molecular landscape and various genetic and epigenetic alterations. Programmed cell death (PCD) plays a critical role in CRC, offering potential targets for therapy by regulating cell elimination processes that can suppress tumor growth or trigger cancer cell resistance. Understanding...
Chiral carbon nanohoops with both high fluorescence quantum yield and large luminescence dissymmetry factor are essential to the development of circularly polarized luminescence (CPL) materials. Herein, the rational design and synthesis of a series of highly fluorescent chiral carbon nanohoops TP‐[8–13]CPPs via symmetry breaking with a chiral triptycene motif is reported. Theoretical calculations...
We reported the synthesis of a series of structurally diverse CPL‐active molecules, in which pyrene units were installed to chiral pm/po‐[2,2]PCP scaffolds either with or without a triple bond spacer for pm/po‐PCP‐P1 and pm/po‐PCP‐P2, respectively. The X‐ray crystallographic analyses revealed that these pyrene‐based [2,2]PCP derivatives exhibited diverse structures and crystal packings in the solid...