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Divergent syntheses of two 14‐membered resorcylic acid lactones (RALs), cochliomycin B (6) and zeaenol (22), have been accomplished. The key feature in our strategy was the facile construction of three contiguous stereogenic centers in the title molecules by using natural L‐arabinose as the chiral template. The key reactions included Takai olefination, Suzuki cross coupling, transesterification, and...
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