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Although the application of 1,2‐dichloroethane (DCE) as a chlorinating reagent in organic synthesis with the concomitant release of vinyl chloride as a useful byproduct is a fantastic idea, it still presents a tremendous challenge and has not yet been achieved because of the harsh dehydrochlorination conditions and the sluggish C−H chlorination process. Here we report a bifunctional electrocatalysis...
Wie aus dem Hut gezaubert liefert eine difunktionale Elektrokatalysestrategie, in der 1,2‐Dichlorethan (DCE) als Quelle für Chlorid und das nützliche Nebenprodukt Vinylchlorid fungiert, (Hetero)Arylchloride. Bei dieser wertschöpfenden Synthese wirkt HCl, das durch katalytische Dehydrierung von DCE gebildet wird, als Chlorierungsmittel, wie N. Jiao et al. in ihrer Zuschrift auf S. 4614 demonstrieren...
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