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New platinum complexes of the type cis‐Pt(L)2Cl2 have been synthesized from five‐ and six‐membered cyclic phosphines, which were prepared after deoxygenating a series of phosphine oxides (3‐phospholene oxides, phospholane oxides, a 1,4‐dihydrophosphinine oxide, and a 1,2,3,6‐tetrahydrophosphinine oxide). The complexes were characterized by NMR and mass spectral data, and their stereostructures were...
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