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Programmable assembly of nanoparticles (NPs) into well‐defined architectures has attracted attention because of tailored properties resulting from coupling effects. However, general and precise approaches to control binding modes between NPs remain a challenge owing to the difficulty in manipulating the accurate positions of the functional patches on the surface of NPs. Here, a strategy is developed...
The thermal response of semi‐dilute solutions (5 w/w%) of two amphiphilic thermoresponsive poly(ethylene oxide)‐b‐poly(N,N‐diethylacrylamide)‐b‐poly(N,N‐dibutylacrylamide) (PEO45‐PDEAmx‐PDBAm12) triblock copolymers, which differ only in the size of the central responsive block, in water was examined. Aqueous PEO45‐PDEAm41‐PDBAm12 solutions, which undergo a thermally induced sphere‐to‐worm transition...
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