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Four lanthanide coordination complexes, namely, [Ln(2,3-DClBA)3(5,5′-dmebipy)(H2O)]2(Ln=Sm(1), Eu(2), Dy(3), Ho(4)); 2,3-DClBA=2,3-dichlorobenzoate; 5,5′-dmebipy=5,5′-dmethylbipyridine) were synthesized and characterized by elemental analysis, infrared spectroscopy and single crystal X-ray diffraction. Findings indicated that complex 3 was a dinuclear molecule, and the center Dy3+ was eight-coordinated...
A ternary complex [Sm(o-NBA) 3 phen] 2 (o-NBA: o-Nitrobenzoate; phen: 1,10-phenanthroline) was synthesized and characterized by elemental analysis, IR, molar conductance, and thermogravimetric analysis. The dissolution enthalpies of SmCl 3 ·6H 2 O(s), o-HNBA(s) and phen·H 2 O(s) in mixed solvent (V HCl :V DMF :V DMSO =2:2:1) were determined...
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