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A facile method for the quantitative preparation of silver dibenzo‐fused corrole Ag‐1 is described. In contrast to the saddle conformation resolved by single‐crystal X‐ray analysis for Ag‐1, it adopts an unprecedented domed geometry, with up and down orientations, when adsorbed on an Ag(111) surface. Sharp Kondo resonances near Fermi level, both at the corrole ligand and the silver center were observed...
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