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An octameric water moiety which consists of a chairlike water hexamer and two pendent water molecules in the 1,4-diaxial positions and shows a similar structure to the hydrocarbon (1r,4r)-1,4-dimethylcyclohexane, is unambiguously trapped in a 2D Cu(II) mixed-ligand coordination polymer, {[Cu2(bpp)2(H2O)2(bpda)2]·6H2O}n (1) (bpp = 1,3-bis(4-pyridyl)propane and H2bpda = 2,2′-biphenyldicarboxylic acid)...
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