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The effect of benzotriazole on the growth of anodic films on aluminium and an Al-3.5wt% Cu alloy has been examined by transmission electron microscopy (TEM) and electrochemical impedance spectroscopy (EIS). Films grown to relatively high voltages reveal flaws and oxygen-filled voids as a result of the surface morphology and copper enrichment and oxidation at the alloy/film interface. Benzotriazole,...
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