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Six zirconocene derivatives were systematically designed; one of the cyclopentadienyl (Cp) ligands of zirconocene dichloride [Cp2ZrCl2] was silylated and this group was then incrementally increased in size; furthermore, one derivative with a 4,4′‐disilylbiphenyl bridge between the two zirconocene fragments was prepared. One zirconium complex was characterized by single‐crystal X‐ray analysis. All...
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