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The alkylation of arylamines using stoichiometric amounts of aliphatic and benzylic alcohols in the presence of tBuOK was carried out at 55 °C using a low catalyst loading of [Ru(cod)Cl2]n/PTA (1,3,5‐triaza‐7‐phosphaadamantane). The overall borrowing‐hydrogen process does not require a controlled nitrogen atmosphere, and it could also be carried out at room temperature using higher loading of base...
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