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A series of halido bis(silylamido) metalates of chromium to cobalt is reported. Reaction of [NBu4]Br with linear metal silylamides ML2 (M=Mn−Co, L=−N(SiMe3)2, −N(Dipp)SiMe3; Dipp=2,6‐iPr−C6H3) leads to NBu4[M(Br)L2] whereas for chromium either intramolecular deprotonation (L=−N(SiMe3)2) or ligand exchange (L=−N(Dipp)SiMe3) is observed. Attempts for their reduction with KC8 showed in part the formation...