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Aromatic species with heavier Group 14 elements show remarkable differences in terms of stability, structure, and reactivity. Herein we report our experimental and theoretical investigations regarding isomers of germanium‐ and tin‐containing benzene analogues E2Si4R6 (E=Ge, Sn). The germanium‐substituted dismutational isomer with a tricyclic six‐membered scaffold is isolable, but unlike the homonuclear...
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