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Tetrad novel Cu-complex containing multifarious meso-10,15,20-Tris (N-methyl-2′-pyridyl)-5-(4′-X-acylhydrazone) porphyrin ligands, where X respectively referred to salicylaldehyde (Cu-P1), o-Vanillin (Cu-P2), pyridine-2-carboxaldehyde (Cu-P3) and acetone (Cu-P4), have been successfully isolated and well characterized. Multiple physicochemical approaches reveal the complex Cu-P4 with preferable binding...
A panel of novel water-soluble Cu(Ⅱ)-based acylhydrazone porphyrin complexes (denoted as Cu-PorX, X = 1, 2 and 3. See Fig. 1) were prepared and characterized. Versatile physicochemical approaches indicated that whole compounds could effectively bind with ct-DNA through intercalative or intercalative coupled with end-stacking interaction, especially, Cu-Por3 has the strongest binding affinity compared...
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