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The influence of the catalyst Sn content on the production of fatty alcohol from oleic acid by selective hydrogenation was studied using Rh‐Sn‐B catalysts supported on TiO2. The crystal phase of the support was analyzed by X‐ray diffraction (XRD), the reduction state of the metal phase by temperature‐programmed reduction (TPR), and the electronic state of surface species by X‐ray photoelectron spectroscopy...