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Die Aktivierung von weißem Phosphor (P4) durch Übergangsmetallkomplexe wird seit Jahrzehnten erforscht, allerdings wurde die Funktionalisierung und Freisetzung der hierbei gebildeten Phosphorliganden vergleichsweise selten realisiert. In dieser Arbeit berichten wir über die Bildung von ungewöhnlichen Diphosphan‐1‐idanionen durch die Reaktion von einem P5‐Liganden mit Cyanidanionen. Neue Cobaltkomplexe...
The chemistry of polyphosphorus cations has rapidly developed in recent years, but their coordination behavior has remained mostly unexplored. Herein, we describe the reactivity of [P5R2]+ cations with cyclopentadienyl metal complexes. The reaction of [CpArFe(μ‐Br)]2 (CpAr=C5(C6H4‐4‐Et)5) with [P5R2][GaCl4] (R=iPr and 2,4,6‐Me3C6H2 (Mes)) afforded bicyclo[1.1.0]pentaphosphanes (1‐R, R=iPr and Mes),...
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