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Die Reaktion von Nickel(0)‐Verbindungen mit weißem Phosphor (P4) ist eine kaum erforschte Syntheseroute für binäre Nickelphosphidcluster. Wir zeigen, dass die Reaktion von P4 mit koordinativ und elektronisch ungesättigten N‐heterocyclischen Carbenkomplexen von Nickel(0) die Darstellung ungewöhnlicher Clusterverbindungen mit P1‐, P3‐, P5‐ und P8‐Einheiten ermöglicht. Die Verwendung von [Ni(IMes)2]...
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