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Gold(I) complexes were readily prepared by reaction of the respective ligands with (Me2S)AuCl in CH2Cl2. Complexes of formula LAuCl {L = diphenyl(2‐pyridyl)phosphane (PPh2Py), (R)‐(+)‐4‐[(2)‐(diphenylphosphanyl)‐1‐naphthyl]‐N‐[(R)‐1‐phenylethyl]‐1‐phthalazinamine (PINAP)} were obtained when a 1:1 molar ratio of ligand to starting gold precursor was used. When a 2:1 ratio of ligand to gold precursor...
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