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The mechanism for catalytic wet air oxidation (CWAO) of ammonia to N2 over Ru–Cu/C catalyst is extensively studied by altering the initial pH, reaction temperature and atmosphere. It is found that N2 formation can be from the catalytically selective oxidation of ammonia or the disproportionation reaction between NH4+ and NO2−. The initial oxidation of ammonia determines the reaction mechanism, the...
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