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Chiral, self‐supported, polytopic imidazoline–pyridine ligands were designed and synthesized for use in Cu catalysis. The tripodal imidazoline–pyridine L6‐Cu(BF4)2 complex catalyzed the asymmetric p‐(tert‐butyl)benzoylation of meso‐hydrobenzoin to give the adduct in up to 85 % ee. After completion of the asymmetric benzoylation reaction, the self‐supported tripodal imidazoline–pyridine–Cu catalyst...
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