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Complexation between thorium(IV) and malonate in 1.05molkg −1 NaClO 4 was studied from 10 to 70°C by potentiometry and calorimetry. Three complexes, ThL 2+ , ThL 2 and ThL 32− , where L stands for malonate, were identified. The stability constants, the enthalpies and entropies of complexation at variable temperatures were determined. Despite that the enthalpies...
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