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Perfluorinated acetic anhydride (PFAA), succinic anhydride (PFSA), and glutaric anhydride (PFGA), were photolyzed at 222 nm. Time-resolved infrared diode laser absorption spectroscopy was used to monitor the CO 2 photoproduct. The CO 2 0n n 0 bending state populations were characterized by vibrational Boltzmann temperatures of 1120 ± 60, 2100 ± 200, and 3100 ± 1000 K for...
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