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Two unprecedented [5+10] icosanuclear molecular 4‐ravels containing four crossings were designed rationally and synthesized successfully using a single‐step strategy as described by Li‐Long Dang, Guo‐Xin Jin et al. in their Research Article (e202301516). This new topology is achieved by utilizing parallel‐displaced π⋅⋅⋅π interactions with carefully selected naphthoquinoyl Cp*M building blocks and...
Intricately interwoven topologies are continually being synthesized and are ultimately equally versatile and significant at the nanoscale level; however, reports concerning ravel structures, which are highly entwined new topological species, are extremely rare and fraught with tremendous synthesis challenges. To solve the synthesis problem, a tetrapodontic pyridine ligand L1 with two types of olefinic...
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