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Adsorption and separation behaviors of ethane/ethylene on ZIF-3, -6, -8 and -10 with different topologies were studied combining Grand canonical Monte Carlo (GCMC) simulations and the ideal adsorbed solution theory (IAST). The simulated single component isotherms indicate that ZIF-3 with the smallest pore size (8.02Å) has the highest adsorption capacity for pure ethane (4.15mmol/g) and ethylene (2...
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