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Two typical electrolytes, i.e., 8YSZ (8mol% yttria-stabilized zirconia) and CGO10 (10mol% Gd-doped ceria), with Si contents of ∼30ppm and ≥500ppm were prepared, whose grain-boundary (GB) conductivities should be controlled by intrinsic (space-charge layer) and extrinsic (resistive siliceous films) effects, respectively. 1at% FeO 1.5 was loaded into these materials via a conventional mixed-oxide...
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