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An efficient route for the catalytic synthesis of aryl amides via the aminocarbonylation of aryl iodides with amines is described using palladium supported on triphenylphosphine-functionalized porous organic polymer (Pd@KAPs(Ph-PPh3)) as the catalyst. Under low carbon monoxide pressure, the catalyst exhibited remarkable activity, and only 0.5 mol% palladium loading was required to achieve moderate...
Catalytic routes for synthesis of alkyl benzoates by alkoxycarbonylation reactions and aryl benzoates by phenoxycarbonylation reactions of aryl iodides are described using a palladium–1,10-phenanthroline complex encaged in Y zeolite. Moderate to excellent yields (40–99 %) of various benzoates were obtained at low Pd loadings of 0.6 mol%. The catalyst could be effectively removed from the reaction...
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