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A β‐cyclodextrin‐based diphosphane with metal‐confining properties was efficiently synthesized thanks to an unprecedented Smiles‐like rearrangement of diphenyl‐(2‐phosphanylphenyl)phosphane in the presence of excess n‐BuLi. The cis‐chelating bidentate ligand is capable of forming very stable heteroleptic [Cu(NN)(PP)]+ complexes in which a metal‐bound diimine ligand (bpy, phen, or mmp) is located within...
Encapsulation makes the difference!. A β‐cyclodextrin‐based diphosphane ligand with metal confining properties is key in the stabilization of heteroleptic Cu(I) complexes. In their Research Article (e202214638), Nicola Armaroli, Béatrice Delavaux‐Nicot, Jean‐François Nierengarten, Dominique Armspach et al. show how encapsulation of the metal‐bound diimine ligand moiety in the cyclodextrin cavity influences...
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