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Utilization of rigid, highly connected organic linkers is critical for the reticular synthesis of functional metal–organic frameworks (MOFs). However, highly‐stable MOFs (e.g. Al/Cr/Zr‐based MOFs) based on rigid ligands with more than 6 coordinating functions have been rarely achieved thus far. Herein, we describe the construction of two bcu Zr‐based MOFs (named ZrMOF‐1 and ZrMOF‐2) from peripherally...
Utilization of rigid, highly connected organic linkers is critical for the reticular synthesis of functional metal–organic frameworks (MOFs). However, highly‐stable MOFs (e.g. Al/Cr/Zr‐based MOFs) based on rigid ligands with more than 6 coordinating functions have been rarely achieved thus far. Herein, we describe the construction of two bcu Zr‐based MOFs (named ZrMOF‐1 and ZrMOF‐2) from peripherally...
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