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Sulfonopeptides as the sulfur analogues of natural peptides have been widely used as enzyme inhibitors due to their tetrahedral sulfonamide moiety, which can mimic the transition‐state analogues of hydrolysis of the ester and amide bonds. Synthetic methods of sulfonopeptides are reviewed. The synthetic methods of sulfonopeptides include the condensation of N‐protected amino acid/peptide acids and...
Phosphonopeptides are important phosphorus analogs of natural peptides and have been widely applied as enzyme inhibitors and antibacterial agents. A series of phosphonodipeptides containing C‐terminal α‐aminoalkylphosphonic acids was synthesized in satisfactory to good yields conveniently from 2‐(N‐benzyloxycarbonylamino)alkanamides, aldehydes, and phosphorus trichloride via Mannich‐type reaction...
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