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Die thermischen Reaktionen von [AuO]+ mit Methan wurden mittels FT‐ICR‐Massenspektrometrie und quantenchemischen Rechnungen untersucht. Im Gegensatz zu den bereits untersuchten Oxiden der 11. Gruppe, [CuO]+ und [AgO]+, reagiert [AuO]+ mit CH4 ausschließlich unter Bildung von CH3OH durch Sauerstoffatomübertragung. Der neuartige Mechanismus dieser spezifischen Oxidation wird vorgestellt und die Ursachen...
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