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In article number 1904689, Qiang Xu and co‐workers present a novel self‐assembly metal–organic framework (MOF)‐templated strategy to fabricate a hydrangea‐like superstructure of open carbon cages with hierarchical porosity and highly active metal sites, leading to control over its assembled structure and functionality. These features result in an extraordinary catalyst in metal–air batteries. This...
Carbon micro‐/nanocages have attracted great attention owing to their wide potential applications. Herein, a self‐templated strategy is presented for the synthesis of a hydrangea‐like superstructure of open carbon cages through morphology‐controlled thermal transformation of core@shell metal–organic frameworks (MOFs). Direct pyrolysis of core@shell zinc (Zn)@cobalt (Co)‐MOFs produces well‐defined...
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