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O Mannosylation is a vital protein modification involved in brain and muscle development whereas the biological relevance of O‐mannosyl glycans has remained largely unknown owing to the lack of structurally defined glycoforms. An efficient scaffold synthesis/enzymatic extension (SSEE) strategy was developed to prepare such structures by combining gram‐scale convergent chemical syntheses of three scaffolds...
Die O‐Mannosylierung ist eine wichtige, im Hirngewebe häufig vorkommende posttranslationale Proteinmodifikation; ihre biologische Bedeutung ist jedoch kaum bekannt. In ihrer Zuschrift auf S. 9412 ff. beschreiben P. G. Wang, L. Li et al. die effiziente Herstellung natürlicher O‐Mannosylglykane durch konvergente Synthese und enzymatische Erweiterung. Diese Glykoformen ermöglichen es, die biologischen...
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