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A novel molecular design for showing near‐infrared (NIR) emission is still required for satisfying growing demands for NIR‐light technology. In this research, hypervalent compounds with germanium (Ge)‐fused azobenzene (GAz) scaffolds were discovered that can exhibit NIR emission (λPL=690∼721 nm, ΦPL=0.03∼0.04) despite compact π‐conjugated systems. The unique optical properties are derived from the...
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