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Hexagonal plate-like Al4Si2C5 particles were synthesized for the first time via a carbothermal reduction process with controlled heating temperature and raw materials ratio, and their oxidation behavior was investigated. Al4O4C, Al2OC, SiC and Al4SiC4 formed as intermediate products when the batch mixture was heated in argon atmosphere, and Al4Si2C5 then formed at above 1800°C. Possible reaction mechanisms...
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