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Es wird über die organokatalytische divergente Synthese von enantiomerenreinen 2H‐ und 3H‐Pyrrolen, unter Verwendung einer Fischer‐Indolisierung und einer [1,5]‐Alkyl‐Verschiebung, berichtet. Katalysiert durch die chirale Phosphorsäure STRIP konnten die entsprechenden Produkte in guten bis exzellenten Ausbeuten sowie Enantioselektivitäten erhalten werden. Bemerkenswerterweise zeigten biologische Untersuchungen,...
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