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Ohne Umweg zu Indolen: Die Titelreaktion liefert Cyclohepta[b]indol‐Derivate in einem einzigen Schritt bei Raumtemperatur (siehe Schema) ohne Ausschluss von Luft und Feuchtigkeit. DFT‐Rechnungen sprechen für eine stufenweise Cyclisierung, und die Vielseitigkeit der Methode wird mit dem zügigen Aufbau einer Bibliothek von Cyclohepta[b]indol‐Analoga demonstriert.
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