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The reaction of trialkylphoshanes and amino-phosphanes with isothiocyanates yields adducts containing the zwitterionic thioamidyl-phosphonium P + C(S)N − functional group. Ligands containing this group were not previously studied, probably due to their instability towards dissociation, in the presence of metal species able to coordinate the P atom. The ligand EtNHC(S)Ph 2 PNPPh...
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