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The reactions of [Fe 2 (CO) 6 (C 2 Et 2 ) 2 ] (complex A) with phosphorus donors in the presence of Me 3 NO results in an unexpected CO insertion to give 'flyover-bridged'' dinuclear compounds. The same reaction also takes place with nitriles giving similar, though less stable, complexes. The reactions of A with terminal alkynes give rise again to...
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