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Composites incorporating nanoparticles (NPs) within metal-organic frameworks (MOFs) find applications in many different fields. In particular, using MOF layers as molecular sieves built on the NPs could enable selectivity in heterogeneous catalysis. However, such composites typically exhibit low catalytic efficiency, due to the slow diffusion of the reactants in the long and narrow channels of the...
The encapsulation of noble‐metal nanoparticles (NPs) in metal‐organic frameworks (MOFs) with carboxylic acid ligands, the most extensive branch of the MOF family, gives NP/MOF composites that exhibit excellent shape‐selective catalytic performance in olefin hydrogenation, aqueous reaction in the reduction of 4‐nitrophenol, and faster molecular diffusion in CO oxidation. The strategy of using functionalized...
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