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The reductive activation of the carbon halogen (C-X) bond is a key step in the transformation of organic halides via bond dissociation. Monochloroacetic acid (MCA), a typical recalcitrant aliphatic halide, was previously shown to be reduced by hydrated electrons (eaq), requiring 254nm irradiation. Here, we demonstrate the efficient hydrogenation of MCA to acetic acid (HOAc) with high selectivity using...
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