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Titanium pyrrolyl complexes Ti(NMe 2 ) 2 (dap) 2 (1), where dap is 2-(N,N-dimethylaminomethyl)pyrrolyl, and Ti(NMe 2 ) 3 (bap) (3), where bap is 2,5-bis(N,N-dimethylaminomethyl)pyrrolyl, were found to be effective catalysts for the iminohydrazination of alkynes, a new multicomponent coupling reaction involving an alkyne, hydrazine, and isonitrile. A brief study...
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