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The α‐arylation of ketones with aryl halides catalyzed by the easily prepared and air‐stable palladium complex (SIPr)Pd(Py)Cl2 (3) is described. Complex 3 displays high activity for a variety of aryl halides (activated, unactivated, and sterically hindered aryl halides) under mild conditions. Moreover, both aryl and alkyl ketones can be arylated. The α‐arylation of some alkyl ketones can even be run...
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